Asymmetric catalysis of carbonyl-ene and aldol reactions with fluoral by chiral binaphthol-derived titanium complex

被引：84

作者：

Mikami, K

Yajima, T

Takasaki, T

Matsukawa, S

Terada, M

Uchimaru, T

Maruta, M

机构：

[1] MINIST INT TRADE & IND,AIST,NATL INST MAT & CHEM RES,TSUKUBA,IBARAKI 305,JAPAN

[2] CENT GLASS CO LTD,TOKYO RES CTR,KAWAGOE,SAITAMA 35011,JAPAN

来源：

TETRAHEDRON | 1996年 / 52卷 / 01期

关键词：

D O I：

10.1016/0040-4020(95)00862-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The chiral titanium complex-catalyzed ene-type reaction and the Mukaiyama aldol reaction with fluoral are shown to serve as an efficient route to the enantioselective and diastereoselective synthesis of CF3-substituted components of biological and synthetic importance.

引用

页码：85 / 98

页数：14

共 54 条

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