Fabrication of semiconductor nanostructures on the outer surfaces of polyacrylonitrile nanofibers by in-situ electrospinning

被引:41
作者
Dong, Fengxia
Li, Zhenyu
Huang, Huiming
Yang, Fan
Zheng, Wei
Wang, Ce [1 ]
机构
[1] Jilin Univ, Alan G MacDiarmid Inst, Changchun 130012, Peoples R China
[2] Jilin Univ, Test Sci Expt Ctr, Changchun 130023, Peoples R China
基金
中国国家自然科学基金;
关键词
heterostructured nanofibers; electrospinning; PAN; semiconductor; outer surface;
D O I
10.1016/j.matlet.2006.09.058
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this paper, in-situ electrospinning method was presented to directly fabricate semiconductor (Ag2S or Cu2S) nanostructures on the outer surfaces of polyacrylonitrile (PAN) nanofibers. PAN/metallic salt composite fibers were electrospun firstly as precursors, after UV irradiation photoreduction and the treatment of H2S gas, Ag2S or Cu2S nanostructures can be obtained on the outer surface of PAN nanofibers. The interactions between the polymer and metallic ions are believed to be the main factor in determining the position of metallic ions based on the electrospun nanofibers. Transmission electron microscopy (TEM) and Fourier transform infrared (FTIR) are used to characterize the products. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:2556 / 2559
页数:4
相关论文
共 33 条
[21]   Nanometre diameter fibres of polymer, produced by electrospinning [J].
Reneker, DH ;
Chun, I .
NANOTECHNOLOGY, 1996, 7 (03) :216-223
[22]   Nanometer-scale switches using copper sulfide [J].
Sakamoto, T ;
Sunamura, H ;
Kawaura, H ;
Hasegawa, T ;
Nakayama, T ;
Aono, M .
APPLIED PHYSICS LETTERS, 2003, 82 (18) :3032-3034
[23]   Two-phase electrospinning from a single electrified jet:: Microencapsulation of aqueous reservoirs in poly(ethylene-co-vinyl acetate) fibers [J].
Sanders, EH ;
Kloefkorn, R ;
Bowlin, GL ;
Simpson, DG ;
Wnek, GE .
MACROMOLECULES, 2003, 36 (11) :3803-3805
[24]   Strong optical limiting of silver-containing nanocrystalline particles in stable suspensions [J].
Sun, YP ;
Riggs, JE ;
Rollins, HW ;
Guduru, R .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (01) :77-82
[25]   Experimental investigation of the governing parameters in the electrospinning of polymer solutions [J].
Theron, SA ;
Zussman, E ;
Yarin, AL .
POLYMER, 2004, 45 (06) :2017-2030
[26]   Electrostatic assembly of conjugated polymer thin layers on electrospun nanofibrous membranes for biosensors [J].
Wang, XY ;
Kim, YG ;
Drew, C ;
Ku, BC ;
Kumar, J ;
Samuelson, LA .
NANO LETTERS, 2004, 4 (02) :331-334
[27]   Electrospun nanofibrous membranes for highly sensitive optical sensors [J].
Wang, XY ;
Drew, C ;
Lee, SH ;
Senecal, KJ ;
Kumar, J ;
Sarnuelson, LA .
NANO LETTERS, 2002, 2 (11) :1273-1275
[28]   Low-temperature synthesis of single crystalline Ag2S nanowires on silver substrates [J].
Wen, XG ;
Wang, SH ;
Xie, YT ;
Li, XY ;
Yang, SH .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (20) :10100-10106
[29]   Electrospinning of nanofiber fibrinogen structures [J].
Wnek, GE ;
Carr, ME ;
Simpson, DG ;
Bowlin, GL .
NANO LETTERS, 2003, 3 (02) :213-216
[30]   Electrospinning and stabilization of fully hydrolyzed poly(vinyl alcohol) fibers [J].
Yao, L ;
Haas, TW ;
Guiseppi-Elie, A ;
Bowlin, GL ;
Simpson, DG ;
Wnek, GE .
CHEMISTRY OF MATERIALS, 2003, 15 (09) :1860-1864