Electrosynthesis of a functional conducting polymer incorporating ferrocene unit from an EDOT-based bithiophenic precursor

被引：15

作者：

Brisset, Hugues

Navarro, Aude-Emmanuelle

Moggia, Fabrice

Jousselme, Bruno

Blanchard, Philippe

Roncali, Jean

机构：

[1] Univ Mediterranee, Lab Mat Mol & Biomat, GCOM2, CNRS,UMR 6114, F-13288 Marseille 9, France

[2] Univ Angers, Grp Syst Conjugues Lineaires, LIMA, CNRS,UMR 6200, F-49045 Angers, France

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2007年 / 603卷 / 01期

关键词：

modified electrodes; ethylenedioxythiophene; electropolymerization; ferrocene;

D O I：

10.1016/j.jelechem.2007.01.017

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A precursor of electrogenerated functional polythiophene combining an EDOT moiety with a thiophene ring on which a ferrocene group is attached at the internal beta-position via a sulphide linkage (1) has been synthesized and characterized. The electrochemical polymerization of this precursor has been investigated in potentiodynamic and potentiostatic conditions. The analysis of the electrochemical behavior of the films growth under various conditions shows that potentiostatic polymerization of 1 in nitrobenzene leads to a polymer which exhibit the electroactivity of the polythiophene backbone and that of the attached ferrocene moiety. (c) 2007 Elsevier B.V. All rights reserved.

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收藏

页码：149 / 154

页数：6

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