Palladium-Catalyzed Dehydrogenative Direct Arylations of 1,2,3-Triazoles

被引：133

作者：

Ackermann, Lutz ^{[1
]}

Jeyachandran, Rajkumar ^{[1
]}

Potukuchi, Harish K. ^{[1
]}

Novak, Petr ^{[1
]}

Buettner, Lea ^{[1
]}

机构：

[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany

来源：

ORGANIC LETTERS | 2010年 / 12卷 / 09期

关键词：

C-H FUNCTIONALIZATION; BOND FORMATION; 1,4-DISUBSTITUTED 1,2,3-TRIAZOLES; 1,3-DIPOLAR CYCLOADDITIONS; ARYL CHLORIDES; ACTIVATION; ARENES; AZIDES; AIR; HETEROCYCLES;

D O I：

10.1021/ol1005517

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium-catalyzed intramolecular dehydrogenative direct arylations of 1,2,3-triazoles were accomplished under ambient pressure of air, which set the stage for a modular synthesis of annulated phenanthrenes through a reaction sequence comprising two distinct catalytic C H bond functionalization reactions.

引用

页码：2056 / 2059

页数：4

共 61 条

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