Reduction of 1,4-dichlorobut-2-yne by titanocene to a 1,2,3-butatriene. Formation of a 1-titanacyclopent-3-yne and a 2,5-dititanabicyclo[2.2.0]hex-1(4)-ene

被引：54

作者：

Burlakov, VV

Arndt, P

Baumann, W

Spannenberg, A

Rosenthal, U

Parameswaran, P

Jemmis, ED

机构：

[1] Univ Rostock eV, Leibniz Inst Organ Katalyse, D-18055 Rostock, Germany

[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 117813, Russia

[3] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 18期

关键词：

D O I：

10.1039/b406494a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 2,5-dititanabicyclo[2.2.0] hex-1(4)-ene (bis-titanocene-mu-(Z)1,2,3- butatriene complex) ( 3) is formed starting from [Cp2Ti(eta(2)-Me3SiC2SiMe3)] by in situ generated titanocene and 1,4-dichlorobut-2-yne via the 1-titanacyclobut-3-yne ( 2).

引用

页码：2074 / 2075

页数：2

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