Non-volatile polymer memory device based on a novel copolymer of N-vinylcarbazole and Eu-complexed vinylbenzoate

被引:246
作者
Ling, QD
Song, Y
Ding, SJ
Zhu, CX
Chan, DSH
Kwong, DL
Kang, ET
Neoh, KG
机构
[1] Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 119260, Singapore
[2] Natl Univ Singapore, Dept Elect & Comp Engn, SNDL, Singapore 119260, Singapore
[3] Univ Texas, Dept Elect & Comp Engn, Austin, TX 78712 USA
关键词
D O I
10.1002/adma.200401048
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A polymer-memory device based on a copolymer containing carbazole (donor) and Eu-complex (acceptor) groups in a metal/insulator/metal architecture is described. The nonvolatile device has two distinctive bistable conductivity states, and exhibits a high ON/OFF current ratio, a fast response time, and acceptable retention under ambient conditions. Application of a potential sets the device to the high-conductivity ON state by generating holes (see Figure).
引用
收藏
页码:455 / +
页数:6
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共 40 条
[11]  
KWOK KS, 2002, MATER TODAY, V5, P28, DOI DOI 10.1016/S1369-7021(02)05227-6
[12]   Mechanism of electron conduction in self-assembled alkanethiol monolayer devices [J].
Lee, TH ;
Wang, WY ;
Reed, MA .
MOLECULAR ELECTRONICS III, 2003, 1006 :21-35
[13]   Fabrication approach for molecular memory arrays [J].
Li, C ;
Zhang, DH ;
Liu, XL ;
Han, S ;
Tang, T ;
Zhou, CW ;
Fan, W ;
Koehne, J ;
Han, J ;
Meyyappan, M ;
Rawlett, AM ;
Price, DW ;
Tour, JM .
APPLIED PHYSICS LETTERS, 2003, 82 (04) :645-647
[14]   Organic electroluminescent devices using europium complex as an electron-transport emitting layer [J].
Liang, CJ ;
Hong, ZR ;
Liu, XY ;
Zhao, DX ;
Zhao, D ;
Li, WL ;
Peng, JB ;
Yu, JQ ;
Lee, CS ;
Lee, ST .
THIN SOLID FILMS, 2000, 359 (01) :14-16
[15]   Monochromatic light-emitting copolymers of N-vinylcarbazole and Eu-complexed 4-vinylbenzoate and their single layer high luminance PLEDs [J].
Ling, QD ;
Cai, QJ ;
Kang, ET ;
Neoh, KG ;
Zhu, FR ;
Huang, W .
JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (18) :2741-2748
[16]   Molecular memories that survive silicon device processing and real-world operation [J].
Liu, ZM ;
Yasseri, AA ;
Lindsey, JS ;
Bocian, DF .
SCIENCE, 2003, 302 (5650) :1543-1545
[17]   Switching and memory devices based on a polythiophene derivative for data-storage applications [J].
Majumdar, HS ;
Bolognesi, A ;
Pal, AJ .
SYNTHETIC METALS, 2004, 140 (2-3) :203-206
[18]   Doped polyaniline polymer fuses: Electrically programmable read-only-memory elements [J].
Marsman, AW ;
Hart, CM ;
Gelinck, GH ;
Geuns, TCT ;
de Leeuw, DM .
JOURNAL OF MATERIALS RESEARCH, 2004, 19 (07) :2057-2060
[19]   THE DESIGN OF ORGANIC METALS - DIBENZOTETRATHIAFULVALENE-2,3-DICHLORO-5,6-DICYANO-PARA-BENZOQUINONE (DBTTF-DDQ) [J].
MAYERLE, JJ ;
TORRANCE, JB .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1981, 54 (10) :3170-3172
[20]   Electrochromic conductive polymer fuses for hybrid organic/inorganic semiconductor memories [J].
Möller, S ;
Forrest, SR ;
Perlov, C ;
Jackson, W ;
Taussig, C .
JOURNAL OF APPLIED PHYSICS, 2003, 94 (12) :7811-7819