Bifunctional AgOAc-catalyzed asymmetric reactions

被引：48

作者：

Chen, Qing-An ^{[1
]}

Wang, Duo-Sheng ^{[1
]}

Zhou, Yong-Gui ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 23期

基金：

中国国家自然科学基金;

关键词：

VINYLOGOUS MANNICH REACTION; 1,3-DIPOLAR CYCLOADDITION REACTIONS; PHASE-TRANSFER CONDITIONS; DIELS-ALDER REACTIONS; GLYCINE SCHIFF-BASES; AZOMETHINE YLIDES; BRONSTED ACID; ENANTIOSELECTIVE SYNTHESIS; CINCHONA ALKALOIDS; CARBONYL-COMPOUNDS;

D O I：

10.1039/c001089h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The discovery and progress of new bifunctional AgOAc-based catalysts for asymmetric reactions is described. In this bifunctional procedure, AgOAc acts as an efficient Lewis acid catalyst as well as a base through the deprotonation of active hydrogen promoted by acetate. The bifunctional strategy offers a great opportunity to establish new fundamentals for stereoselective construction of C-C as well as C-N bonds.

引用

页码：4043 / 4051

页数：9

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