Cationic Palladium(II) Catalysis: C-H Activation/Suzuki-Miyaura Couplings at Room Temperature

被引：245

作者：

Nishikata, Takashi ^{[1
]}

Abela, Alexander R. ^{[1
]}

Huang, Shenlin ^{[1
]}

Lipshutz, Bruce H. ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 14期

关键词：

PROTON-ABSTRACTION MECHANISM; DIRECT C-2 ARYLATION; ARYLBORONIC ACIDS; BOND ACTIVATION; BORONIC ACIDS; CONJUGATE ADDITION; AROMATIC-COMPOUNDS; PD; (HETERO)ARENES; 1,4-ADDITION;

D O I：

10.1021/ja910973a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cationic palladium(II) catalyst realized facile C-H activation of aryl urea with arylboronic acids at room temperature. This reaction is extremely mild to carry out aromatic C-H activations through electrophilic substitution.

引用

页码：4978 / +

页数：3

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