High-color-rendering pure-white phosphorescent organic light-emitting devices employing only two complementary colors

被引:63
作者
Chang, Chih-Hao [1 ]
Chen, Chung-Chia [1 ]
Wu, Chung-Chih [1 ]
Chang, Sheng-Yuan [2 ]
Hung, Jui-Yi [2 ]
Chi, Yun [2 ]
机构
[1] Natl Taiwan Univ, Dept Elect Engn, Grad Inst Photon & Optoelect, Grad Inst Elect Engn, Taipei 10617, Taiwan
[2] Natl Tsing Hua Univ, Dept Chem, Hsinchu 300, Taiwan
关键词
Osmium complex; Iridium complex; White OLEDs; Color rendering index; HIGH-EFFICIENCY; ELECTROPHOSPHORESCENT DEVICES; QUANTUM EFFICIENCY; TRIPLET EXCITONS; ORANGE PHOSPHOR; DOUBLE-EMISSION; BLUE; DIODES; OLEDS; COMPLEXES;
D O I
10.1016/j.orgel.2009.11.004
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We report successful fabrication of high-color-rendering pure-white phosphorescent organic light-emitting devices (OLEDs) by employing a true-blue iridium complex Ir(dfbp-py)(fbppz)(2) and a wide-bandwidth yellow emitting osmium complex Os(bptz)(2)(dppee). The two-component phosphorescent white OLED exhibited a high color rendering index (CRI) of 81 and CIEx,y coordinates close to the ideal white emission (0.33, 0.33). By doping the yellow phosphors into the hole-transport layer and the electron-transport layer adjacent to the blue-emitting layer and thereby forming a triple-emitting-layer device structure, we obtained WOLED which exhibited rather stable colors at different biases/brightnesses. Such high-CRI pure-white two-component WOLEDs yielded EL efficiencies of up to 9.5%, 22.9 cd/A, and 20 lm/W for the forward directions. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:266 / 272
页数:7
相关论文
共 34 条
[1]   New charge-carrier blocking materials for high efficiency OLEDs [J].
Adamovich, VI ;
Cordero, SR ;
Djurovich, PI ;
Tamayo, A ;
Thompson, ME ;
D'Andrade, BW ;
Forrest, SR .
ORGANIC ELECTRONICS, 2003, 4 (2-3) :77-87
[2]   Study of organic light emitting devices with a 5,6,11,12-tetraphenylnaphthacene (rubrene)-doped hole transport layer [J].
Aziz, H ;
Popovic, ZD .
APPLIED PHYSICS LETTERS, 2002, 80 (12) :2180-2182
[3]   Efficient white OLEDs employing phosphorescent sensitization [J].
Chang, Chih-Hao ;
Lu, Yin-Jui ;
Liu, Chih-Che ;
Yeh, Yung-Hui ;
Wu, Chung-Chih .
JOURNAL OF DISPLAY TECHNOLOGY, 2007, 3 (02) :193-199
[4]   Efficient iridium(III) based, true-blue emitting phosphorescent OLEDS employing both double emission and double buffer layers [J].
Chang, Chih-Hao ;
Chen, Chung-Chia ;
Wu, Chung-Chih ;
Yang, Cheng-Han ;
Chi, Yun .
ORGANIC ELECTRONICS, 2009, 10 (07) :1364-1371
[5]   Efficient phosphorescent white organic light-emitting devices incorporating blue iridium complex and multifunctional orange-red osmium complex [J].
Chang, Chih-Hao ;
Lin, You-Heng ;
Chen, Chung-Chia ;
Chang, Chih-Kai ;
Wu, Chung-Chih ;
Chen, Li-Shiuan ;
Wu, Wen-Wen ;
Chi, Yun .
ORGANIC ELECTRONICS, 2009, 10 (07) :1235-1240
[6]   Highly efficient blue-emitting iridium(III) carbene complexes and phosphorescent OLEDs [J].
Chang, Chiung-Fang ;
Cheng, Yi-Ming ;
Chi, Yun ;
Chiu, Yuan-Chieh ;
Lin, Chao-Chen ;
Lee, Gene-Hsiang ;
Chou, Pi-Tai ;
Chen, Chung-Chia ;
Chang, Chih-Hao ;
Wu, Chung-Chih .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (24) :4542-4545
[7]   Rational design of Chelating phosphine functionalized Os(II) emitters and fabrication of orange polymer light-emitting diodes using solution process [J].
Cheng, Yi-Ming ;
Lee, Gene-Hsiang ;
Chou, Pi-Tai ;
Chen, Li-Shiuan ;
Chi, Yun ;
Yang, Cheng-Han ;
Song, Yi-Hwa ;
Chang, Sheng-Yuan ;
Shih, Ping-I. ;
Shu, Ching-Fong .
ADVANCED FUNCTIONAL MATERIALS, 2008, 18 (02) :183-194
[8]   En Route to High External Quantum Efficiency (∼12%), Organic True-Blue-Light-Emitting Diodes Employing Novel Design of Iridium (III) Phosphors [J].
Chiu, Yuan-Chieh ;
Hung, Jui-Yi ;
Chi, Yun ;
Chen, Chung-Chia ;
Chang, Chih-Hao ;
Wu, Chung-Chih ;
Cheng, Yi-Ming ;
Yu, Ya-Chien ;
Lee, Gene-Hsiang ;
Chou, Pi-Tai .
ADVANCED MATERIALS, 2009, 21 (21) :2221-+
[9]   Organic light-emitting device luminaire for illumination applications [J].
D'Andrade, BW ;
Brown, JJ .
APPLIED PHYSICS LETTERS, 2006, 88 (19)
[10]   Relationship between the ionization and oxidation potentials of molecular organic semiconductors [J].
D'Andrade, BW ;
Datta, S ;
Forrest, SR ;
Djurovich, P ;
Polikarpov, E ;
Thompson, ME .
ORGANIC ELECTRONICS, 2005, 6 (01) :11-20