Effect of bias treatment in the CVD diamond growth on Ir(001)

被引:17
作者
Kono, S
Takano, I
Goto, I
Ikejima, Y
Shiraishi, M
Abukawa, T
Yamada, T
Sawabe, A
机构
[1] Tohoku Univ, IMRAM, Aoba Ku, Sendai, Miyagi 9808577, Japan
[2] Aoyama Gakuin Univ, Dept Elect Engn, Sagamihara, Kanagawa 2298558, Japan
关键词
diamond growth and characterisation; CVD hetero-epitaxial diamond (001); X-ray photoelectron diffraction; Ir(001) substrate;
D O I
10.1016/j.diamond.2004.07.009
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The effect of bias treatment (BT) on direct-current plasma CVD diamond growth has been studied in situ by X-ray photoelectron diffraction (XPD) together with LEED and XPS. It was found that C 1s XPD patterns from the sample after BT are similar to those of diamond (001). Coverage of carbon after BT is several tens of ML when BT is very successful. However, LEED shows no diamond (001) spots for the sample after BT. These apparently contradictory findings are explained by the sizes of the diamond (001) crystallites, which, after BT, are large enough to produce C 1s XPD patterns of diamond, but too small to have coherent interference spots in LEED. It is concluded from this and other information that BT in a DC plasma creates hetero-epitaxial diamond crystallites a few nm or less. These diamond crystallites may be related to the atomically abrupt diamond/Ir interfaces of DC plasma CVD-grown samples revealed by TEM [A. Sawabe H. Fukuda, T. Suzuki, Y. Ikuhara, T. Suzuki, Surf. Sci. 467 (2000) L845]. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:2081 / 2087
页数:7
相关论文
共 16 条
[1]   Application of CVD-diamond for catheter ablation in the heart [J].
Müller, R ;
Adamschik, M ;
Steidl, D ;
Kohn, E ;
Thamasett, S ;
Stiller, S ;
Hanke, H ;
Hombach, V .
DIAMOND AND RELATED MATERIALS, 2004, 13 (4-8) :1080-1083
[2]   Highly oriented diamond films on heterosubstrates: Current state of the art and remaining challenges [J].
Arnault, JC .
SURFACE REVIEW AND LETTERS, 2003, 10 (01) :127-146
[3]   Studies of heteroepitaxial growth of diamond [J].
Bednarski, C ;
Dai, Z ;
Li, AP ;
Golding, B .
DIAMOND AND RELATED MATERIALS, 2003, 12 (3-7) :241-245
[4]   Convergence and reliability of the Rehr-Albers formalism in multiple-scattering calculations of photoelectron diffraction [J].
Chen, Y ;
de Abajo, FJG ;
Chasse, A ;
Ynzunza, RX ;
Kaduwela, AP ;
Van Hove, MA ;
Fadley, CS .
PHYSICAL REVIEW B, 1998, 58 (19) :13121-13131
[5]   Epitaxial (100) iridium on A-plane sapphire:: A system for wafer-scale diamond heteroepitaxy [J].
Dai, Z ;
Bednarski-Meinke, C ;
Loloee, R ;
Golding, B .
APPLIED PHYSICS LETTERS, 2003, 82 (22) :3847-3849
[6]   Initial growth of heteroepitaxial diamond on Ir(001)/MgO(001) substrates using antenna-edge-type microwave plasma assisted chemical vapor deposition [J].
Fujisaki, T ;
Tachiki, M ;
Taniyama, N ;
Kudo, M ;
Kawarada, H .
DIAMOND AND RELATED MATERIALS, 2003, 12 (3-7) :246-250
[7]   Flat epitaxial diamond/Ir(001) interface visualized by high resolution transmission electron microscopy [J].
Hörmann, F ;
Peng, HY ;
Bauer, T ;
Li, Q ;
Schreck, M ;
Lifshitz, Y ;
Lee, ST ;
Stritzker, B .
SURFACE SCIENCE, 2002, 513 (03) :525-529
[8]   Electron-spectroscopy and -diffraction study of the conductivity of CVD diamond (001)2 x 1 surface [J].
Kono, S ;
Takano, T ;
Shimomura, M ;
Goto, T ;
Sato, K ;
Abukawa, T ;
Tachiki, M ;
Kawarada, H .
SURFACE SCIENCE, 2003, 529 (1-2) :180-188
[9]   Photoelectron diffraction study of the structures of silicon surfaces [J].
Kono, S .
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 2002, 126 (1-3) :43-53
[10]   Epitaxial growth of diamond on iridium [J].
Ohtsuka, K ;
Suzuki, K ;
Sawabe, A ;
Inuzuka, T .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 1996, 35 (8B) :L1072-L1074