A novel two-dimensional organic-inorganic hybrid compound with a (4,6)-lattice-type network:: {[Co(H2O)2][Co2(phen)2(btc)2]}n(btc = benzene-1,2,4-tricarboxylate)

被引：9

作者：

Hao, N

Liu, FC

Wang, EB ^{[1
]}

Huang, RD

Li, YG

Hu, CW

机构：

[1] NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Jilin, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

[3] Beijing Inst Technol, Dept Chem, Sch Chem Engn & Mat, Beijing 100081, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 06期

基金：

中国国家自然科学基金;

关键词：

coordination polymer; metal-organic network; hydrothermal synthesis; crystal structure;

D O I：

10.1016/S1387-7003(03)00094-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new organic-inorganic hybrid compound {[Co(H2O)(2)][Co-2(phen)(2)(btc)(2)]}(n) 1 has been hydrothermally synthesized and characterized by elemental analyses, IR spectrum, TG analysis and single-crystal X-ray diffraction. Compound 1 crystallizes in the triclinic system, space group P (1) over bar, a = 7.7709(16) Angstrom, b = 10.572(2) Angstrom, c = 12.178(2) Angstrom, alpha = 88.49(3)degrees, beta = 77.97(3)degrees, gamma = 69.84(3)degrees, V = 917.5(3) Angstrom(3), Z = 1, R1 = 0.0571. The compound 1 exhibits a novel two-dimensional network with unusual (4,6)-lattice-type network constructed by [Co-2(phen)(2)(btc)(2)](2-) dimers and the [Co(H2O)(2)](2+), fragments. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：728 / 732

页数：5

共 26 条

[11] A porous chiral framework of coordinated 1,3,5-benzenetricarboxylate: quadruple interpenetration of the (10,3)-a network [J].