A New Multidentate Hexacarboxylic Acid for the Construction of Porous Metal-Organic Frameworks of Diverse Structures and Porosities

被引：48

作者：

Chen, Zhenxia ^{[1
,2
]}

Xiang, Shengchang ^{[2
]}

Liao, Tengbiao ^{[1
]}

Yang, Yongtai ^{[1
]}

Chen, Yu-Sheng ^{[3
]}

Zhou, Yaming ^{[1
]}

Zhao, Dongyuan ^{[1
]}

Chen, Banglin ^{[2
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

[2] Univ Texas San Antonio, Dept Chem, San Antonio, TX 78249 USA

[3] Univ Chicago, ChemMatCARS, Ctr Adv Radiat Sources, Argonne, IL 60439 USA

来源：

CRYSTAL GROWTH & DESIGN | 2010年 / 10卷 / 06期

基金：

美国国家科学基金会;

关键词：

HIGH H-2 ADSORPTION; HYDROGEN STORAGE; 3-PERIODIC NETS; SURFACE-AREA; DESIGN; SITES; TILINGS; SOLIDS; CAGES;

D O I：

10.1021/cg100316s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three porous metal organic frameworks have been constructed from the new developed C3-symmetric hexacarboxylic acid 3,3',3 '',5,5',5 ''-benzene-1,3,5-triyl-hexabenzoic acid (H(6)BHB) of different NaCl- and Al(2)O(3)-type topologies. The activated metal-organic frameworks (MOFs) exhibit permanent porosities as revealed in their gas and vapor adsorption isotherms, highlighting the promise of this new ligand for the construction of porous MOFs for gas storage and separation.

引用

页码：2775 / 2779

页数：5

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