Growth and characterization of silicon carbide nanowires

被引:29
作者
Park, BT [1 ]
Ryu, YW [1 ]
Yong, KJ [1 ]
机构
[1] Pohang Univ Sci & Technol, POSTECH, Surface Chem Lab Elect Mat, Dept Chem Engn, Pohang 790784, South Korea
关键词
low dimensional structures; nanowires; growth models; SiC;
D O I
10.1142/S0218625X04006311
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A simple, direct synthesis method was used to grow the core-shell SiC-SiOx nanowires by heating the NiO catalyzed silicon substrate. The carbothermal reduction of WO3 by C provided a reductive environment to synthesize the crystalline SiC nanowires covered with the SiOx sheath in the growth temperature of 1000-1100degreesC. After hydrofluoric acid (HF) etching, the cubic beta-SiC nanowires were extracted from the core-shell nanowires in large quantities. A solid-liquid-solid (SLS) mechanism was proposed for the growth of the core-shell SiC-SiOx nanowires.
引用
收藏
页码:373 / 378
页数:6
相关论文
共 21 条
[1]   INFRARED-SPECTROSCOPY OF SI(111) SURFACES AFTER HF TREATMENT - HYDROGEN TERMINATION AND SURFACE-MORPHOLOGY [J].
BURROWS, VA ;
CHABAL, YJ ;
HIGASHI, GS ;
RAGHAVACHARI, K ;
CHRISTMAN, SB .
APPLIED PHYSICS LETTERS, 1988, 53 (11) :998-1000
[2]  
Duan XF, 2000, ADV MATER, V12, P298, DOI 10.1002/(SICI)1521-4095(200002)12:4<298::AID-ADMA298>3.0.CO
[3]  
2-Y
[4]   IDEAL HYDROGEN TERMINATION OF THE SI-(111) SURFACE [J].
HIGASHI, GS ;
CHABAL, YJ ;
TRUCKS, GW ;
RAGHAVACHARI, K .
APPLIED PHYSICS LETTERS, 1990, 56 (07) :656-658
[5]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58
[6]   SiC nanowire networks [J].
Li, HJ ;
Li, ZJ ;
Meng, AL ;
Li, KZ ;
Zhang, XN ;
Xu, YP .
JOURNAL OF ALLOYS AND COMPOUNDS, 2003, 352 (1-2) :279-282
[7]   A simple large-scale synthesis of coaxial nanocables: silicon carbide sheathed with silicon oxide [J].
Liu, DF ;
Xie, SS ;
Yan, XQ ;
Ci, LJ ;
Shen, F ;
Wang, JX ;
Zhou, ZP ;
Yuan, HJ ;
Gao, Y ;
Song, L ;
Liu, LF ;
Zhou, WY ;
Wang, G .
CHEMICAL PHYSICS LETTERS, 2003, 375 (3-4) :269-272
[8]   Catalytic synthesis and photoluminescence of gallium nitride nanowires [J].
Lyu, SC ;
Cha, OH ;
Suh, EK ;
Ruh, H ;
Lee, HJ ;
Lee, CJ .
CHEMICAL PHYSICS LETTERS, 2003, 367 (1-2) :136-140
[9]   Low temperature growth and photoluminescence of well-aligned zinc oxide nanowires [J].
Lyu, SC ;
Zhang, Y ;
Ruh, H ;
Lee, HJ ;
Shim, HW ;
Suh, EK ;
Lee, CJ .
CHEMICAL PHYSICS LETTERS, 2002, 363 (1-2) :134-138
[10]   Oxidation processes on the H2O chemisorbed Si(100) surface studied by in-situ infrared spectroscopy [J].
Niwano, M ;
Terashi, M ;
Shinohara, M ;
Shoji, D ;
Miyamoto, N .
SURFACE SCIENCE, 1998, 401 (03) :364-370