A simple and novel eco-friendly process for the one-pot synthesis of dithiocarbamates from amines, carbon disulfide, and epoxides

被引：57

作者：

Azizi, Najmedin

Pourhasan, Bahram

Aryanasab, Fezzeh

Saidi, Mohammad R.

机构：

[1] Sharif Univ Technol, Dept Chem, Tehran 11365, Iran

[2] Chem & Chem Engn Res Ctr Iran, Tehran 11365, Iran

来源：

SYNLETT | 2007年 / 08期

关键词：

atom economy; dithiocarbamate; epoxide; amine; solvent-free;

D O I：

10.1055/s-2007-977450

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An environmentally benign, highly efficient, and simple protocol for the synthesis of various structurally divergent dithiocarbamate derivatives in one-pot reaction of amines, carbon disulfide, and epoxides, without using any solvent and catalyst at room temperature, is presented. This new procedure has the advantages of higher yield, lower cost, reduced environmental impact, and simple work-up procedure.

引用

收藏

页码：1239 / 1242

页数：4

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