Development and utility of manganese oxides as cathodes in lithium batteries

被引：115

作者：

Johnson, Christopher S. ^{[1
]}

机构：

[1] Argonne Natl Lab, Chem Engn Divelectrochem Technol Program, Argonne, IL 60439 USA

来源：

JOURNAL OF POWER SOURCES | 2007年 / 165卷 / 02期

关键词：

lithium battery; composite electrode; alpha-MnO2; manganese oxide; Li2MnO3;

D O I：

10.1016/j.jpowsour.2006.10.040

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Manganese oxides have a long history of serving as a cathode in charge storage applications. Electrolytic manganese dioxide (EMD) is widely used in alkaline batteries and MnO2 originally was part of the Leclanche wet cell patented in 1866. Leclanche wet cells used a naturally occurring MnO2 ore with Zn metal as anode and ammonium chloride electrolyte. While there are a vast number of topics to discuss on manganese oxides, in this short paper, two topics researched at Argonne over the last 12 years are highlighted. First, the addition of lithia (Li2O) as a stabilizing component in 3 V alpha-MnO2 is examined. Second, an overview of the evolution of layered-layered composite-structured electrodes derived from the lithium-manganese oxide (Li2MnO3) layered rock-salt phase is presented. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：559 / 565

页数：7

共 39 条

[11] Ammonia- and lithia-doped manganese dioxide for 3 V lithium batteries [J].

Johnson, CS ;

Thackeray, MM .

JOURNAL OF POWER SOURCES, 2001, 97-8 :437-442

[12]

Johnson CS, 1998, J POWER SOURCES, V75, P183

[13]

JOHNSON CS, 2001, P ELECTROCHEMICAL SO, P47

[14]

JOHNSON CS, 1995, UNPUB

[15] Electrochemical and structural properties of xLi2M'O3•(1-x)LiMn0.5Ni0.5O2 eIectrodes for lithium batteries (M' = Ti, Mn, Zr; 0 ≤ x ≤ 0.3) [J].

Kim, JS ;

Johnson, CS ;

Vaughey, JT ;

Thackeray, MM ;

Hackney, SA .

CHEMISTRY OF MATERIALS, 2004, 16 (10) :1996-2006

[16] Layered xLiMO2 • (1-x)Li2M′O3 electrodes for lithium batteries:: a study of 0.95LiMn0.5Ni0.5O2 • 0.05Li2TiO3 [J].

Kim, JS ;

Johnson, CS ;

Thackeray, MM .

ELECTROCHEMISTRY COMMUNICATIONS, 2002, 4 (03) :205-209

[17] Low temperature synthesis of γ-LixMnO2 powders in ethylene glycol [J].

Larcher, D ;

Gérand, B ;

Tarascon, JM .

INTERNATIONAL JOURNAL OF INORGANIC MATERIALS, 2000, 2 (05) :389-396

[18] A comparison of the electrode/electrolyte reaction at elevated temperatures for various Li-ion battery cathodes [J].

MacNeil, DD ;

Lu, ZH ;

Chen, ZH ;

Dahn, JR .

JOURNAL OF POWER SOURCES, 2002, 108 (1-2) :8-14

[19] Lithiated manganese oxides as a cathode for lithium batteries [J].

Nakamura, H ;

Motooka, K ;

Noguchi, H ;

Yoshio, M .

JOURNAL OF POWER SOURCES, 1999, 81 :632-636

[20] MANGANESE OXIDES FOR A LITHIUM SECONDARY BATTERY - COMPOSITE DIMENSIONAL MANGANESE OXIDE (CDMO) [J].

NOHMA, T ;

SAITO, T ;

FURUKAWA, N ;

IKEDA, H .

JOURNAL OF POWER SOURCES, 1989, 26 (3-4) :389-396

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