Conducting organic radical cation salts with organic and organometallic anions

被引：101

作者：

Geiser, U ^{[1
]}

Schlueter, JA ^{[1
]}

机构：

[1] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA

来源：

CHEMICAL REVIEWS | 2004年 / 104卷 / 11期

关键词：

D O I：

10.1021/cr0306844

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The discovery of high electrical conductivity in an organic complex in 1954 stimulated a great deal of research in the field of molecular conductors. To date, a large number of electron-donor and -acceptor molecules have been synthesized, and conducting salts thereof have been crystallized. This review summarizes all the work that has been carried out on the conducting salts that are formed between molecular radical cations and organic and organometallic anions. Focus is on anions that are introduced already in the form of anions with a well-defined charge state, while the radical cations are generated oxidatively during the crystallization process.

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页码：5203 / 5241

页数：39

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