Reactions of phenyldimethylsilyllithium with β-N,N-dimethylaminoenones

被引：7

作者：

Fleming, I ^{[1
]}

Marangon, E ^{[1
]}

Roni, C ^{[1
]}

Russell, MG ^{[1
]}

Chamudis, ST ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 02期

关键词：

D O I：

10.1039/b210444j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Phenyldimethylsilyllithium reacts with the beta-N,N-dimethylaminoenones 1 and 7, with the enal 5, and with ethyl beta-N, N-dimethylaminoacrylate 9 to give the corresponding alpha,beta-unsaturated carbonyl compounds with a beta-phenyl-dimethylsilyl group, but in the last case only when the reaction mixture is given a mysteriously brief treatment with methyl iodide before workup.

引用

页码：200 / 201

页数：2

共 18 条

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