Mesoporous TS-1: Nanocasting synthesis with CMK-3 as template and its performance in catalytic oxidation of aromatic thiophene

被引：110

作者：

Fang, Yunming ^{[1
]}

Hu, Haoquan ^{[1
]}

机构：

[1] Dalian Univ Technol, Inst Coal Chem Engn, State Key Lab Fine Chem, Dalian 116012, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2007年 / 8卷 / 05期

基金：

中国国家自然科学基金;

关键词：

mesoporous TS-1; nanocasting; catalytic oxidation; desulfurization;

D O I：

10.1016/j.catcom.2006.09.018

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mesoporous TS-1, with additional mesopore system formed by packing the TS-1 nanocrystals, was synthesized by nanocasting route using nanoporous carbon (CMK-3) as template and characterized by XRD, BET, TEM, UV-vis and FT-IR. Catalytic performance of mesoporous TS-1 in H2O2 oxidation of aromatic thiophene, the model sulfur containing molecule in transportation fuels, was tested and reported. Compared with common TS-1, mesoporous TS-1 shows improved catalytic performance for thiophene oxidation and is able to catalyze oxidation of bulky sulfur containing molecule such as dimethyldibenzothiophene. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：817 / 820

页数：4

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