Preparation of metal-imidazolidin-2-ylidene complexes by oxidative addition

被引：105

作者：

Fürstner, A ^{[1
]}

Seidel, G ^{[1
]}

Kremzow, D ^{[1
]}

Lehmann, CW ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 05期

关键词：

D O I：

10.1021/om021022s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An entry into (chiral) palladium complexes bearing N-heterocyclic carbene (NHC) ligands is outlined on the basis of the oxidative addition of Pd(PPh3)(4) to easily accessible (enantiopure) 2-chloro-1,3-disubstituted imidazolinium salts. This procedure is complementary to existing methodology that relies on metathetic ligand exchange reactions without changing the oxidation state of the involved metal center.

引用

页码：907 / 909

页数：3

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