Very High Mobility in Solution-Processed Organic Thin-Film Transistors of Highly Ordered [1]Benzothieno[3,2-b]benzothiophene Derivatives

被引：252

作者：

Uemura, Takafumi ^{[1
]}

Hirose, Yuri ^{[1
]}

Uno, Mayumi ^{[1
]}

Takimiya, Kazuo ^{[2
]}

Takeya, Jun ^{[1
,3
]}

机构：

[1] Osaka Univ, Grad Sch Sci, Osaka 5600043, Japan

[2] Hiroshima Univ, Grad Sch Engn, Dept Appl Chem, Hiroshima 7398527, Japan

[3] Japan Sci & Technol Agcy, PRESTO, Kawaguchi, Saitama 3330012, Japan

来源：

APPLIED PHYSICS EXPRESS | 2009年 / 2卷 / 11期

关键词：

FIELD-EFFECT TRANSISTORS; HIGH-PERFORMANCE; CHARGE-TRANSPORT; SINGLE-CRYSTALS; PENTACENE; SURFACE;

D O I：

10.1143/APEX.2.111501

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

Field-effect mobility as high as 5 cm(2)/(V S) is achieved in solution-processed organic thin-film transistors with the development of a method for growing highly-oriented crystalline films of [1]benzothieno[3,2-b]benzothiophene derivatives. A droplet of the solution is sustained at an edge of a structure on an inclined substrate, so that the crystalline domain grows in the direction of inclination. The oriented growth realizes excellent molecular ordering that manifests itself in micrometer-scale molecular terraces on the surface as a result of the self-organizing function of the material. The unprecedented performance achieved using an easy fabrication process has increased attractiveness of organic thin-film transistors for industrial applications. (C) 2009 The Japan Society of Applied Physics

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页数：3

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共 19 条

[1] Functionalized pentacene: Improved electronic properties from control of solid-state order [J].

Anthony, JE ;

Brooks, JS ;

Eaton, DL ;

Parkin, SR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (38) :9482-9483

[2] Field-effect transistors on tetracene single crystals [J].

de Boer, RWI ;

Klapwijk, TM ;

Morpurgo, AF .

APPLIED PHYSICS LETTERS, 2003, 83 (21) :4345-4347

[3] Improving organic thin-film transistor performance through solvent-vapor annealing of solution-processable triethylsilylethynyl anthradithiophene [J].

Dickey, Kimberly C. ;

Anthony, John E. ;

Loo, Yueh-Lin .

ADVANCED MATERIALS, 2006, 18 (13) :1721-+

[4] Highly soluble [1]benzothieno[3,2-b]benzothiophene (BTBT) derivatives for high-performance, solution-processed organic field-effect transistors [J].

Ebata, Hideaki ;

Izawa, Takafumi ;

Miyazaki, Eigo ;

Takimiya, Kazuo ;

Ikeda, Masaaki ;

Kuwabara, Hirokazu ;

Yui, Tatsuto .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (51) :15732-+

[5] Molecular ordering of high-performance soluble molecular semiconductors and re-evaluation of their field-effect transistor characteristics [J].

Izawa, Takafumi ;

Miyazaki, Eigo ;

Takimiya, Kazuo .

ADVANCED MATERIALS, 2008, 20 (18) :3388-+

[6] Light quasiparticles dominate electronic transport in molecular crystal field-effect transistors [J].

Li, Z. Q. ;

Podzorov, V. ;

Sai, N. ;

Martin, M. C. ;

Gershenson, M. E. ;

Di Ventra, M. ;

Basov, D. N. .

PHYSICAL REVIEW LETTERS, 2007, 99 (01)

[7] Liquid-crystalline semiconducting polymers with high charge-carrier mobility [J].

Mcculloch, I ;

Heeney, M ;

Bailey, C ;

Genevicius, K ;

Macdonald, I ;

Shkunov, M ;

Sparrowe, D ;

Tierney, S ;

Wagner, R ;

Zhang, WM ;

Chabinyc, ML ;

Kline, RJ ;

Mcgehee, MD ;

Toney, MF .

NATURE MATERIALS, 2006, 5 (04) :328-333

[8] High-performance n- and p-type single-crystal organic transistors with free-space gate dielectrics [J].

Menard, E ;

Podzorov, V ;

Hur, SH ;

Gaur, A ;

Gershenson, ME ;

Rogers, JA .

ADVANCED MATERIALS, 2004, 16 (23-24) :2097-2101

[9] Nanoscale surface morphology and rectifying behavior of a bulk single-crystal organic semiconductor [J].

Menard, Etienne ;

Marchenko, Alexandr ;

Podzorov, Vitaly ;

Gershenson, Michael E. ;

Fichou, Denis ;

Rogers, John A. .

ADVANCED MATERIALS, 2006, 18 (12) :1552-+

[10] Surface selective deposition of molecular semiconductors for solution-based integration of organic field-effect transistors [J].

Minari, Takeo ;

Kano, Masataka ;

Miyadera, Tetsuhiko ;

Wang, Sui-Dong ;

Aoyagi, Yoshinobu ;

Tsukagoshi, Kazuhito .

APPLIED PHYSICS LETTERS, 2009, 94 (09)