Coordination, organometallic and related chemistry of tris(pyrazolyl) methane ligands

被引:238
作者
Bigmore, HR [1 ]
Lawrence, SC [1 ]
Mountford, P [1 ]
Tredget, CS [1 ]
机构
[1] Univ Oxford, Chem Res Lab, Oxford OX1 3TA, England
关键词
D O I
10.1039/b413121e
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Tris( pyrazolyl) methanes are the neutral analogues of the widely exploited and highly useful tris( pyrazolyl) hydroborates, yet by comparison with their boron based counterparts their chemistry is underdeveloped. Recent breakthroughs in the synthesis of ring-substituted tris(pyrazolyl) methanes offer the opportunity for the development of this useful and promising class of ligand. This review summarises the current state of the coordination and organometallic chemistry of tris(pyrazolyl) methanes and highlights areas in which development is likely to occur.
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收藏
页码:635 / 651
页数:17
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