Rhodium-Catalyzed Oxidative Coupling/Cyclization of 2-Phenylindoles with Alkynes via C-H and N-H Bond Cleavages with Air as the Oxidant

被引：259

作者：

Morimoto, Keisuke ^{[1
]}

Hirano, Koji ^{[1
]}

Satoh, Tetsuya ^{[1
]}

Miura, Masahiro ^{[1
]}

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

来源：

ORGANIC LETTERS | 2010年 / 12卷 / 09期

关键词：

HETEROARENE CARBOXYLIC-ACIDS; FLUORESCENT PROPERTIES; NITROGEN-HETEROCYCLES; INTERNAL ALKYNES; ARYLATION; ACTIVATION; FUNCTIONALIZATION; MULTIPLE;

D O I：

10.1021/ol100560k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The straightforward and efficient synthesis of indolo[2,1-a]isoguinoline derivatives has been achieved by the rhodium-catalyzed aerobic oxidative coupling/cyclization of 2-phenylindoles with alkynes. Some of the polycyclic products exhibit solid-state fluorescence.

引用

页码：2068 / 2071

页数：4

共 49 条

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