Transparent, conductive carbon nanotube films

被引:2614
作者
Wu, ZC
Chen, ZH
Du, X
Logan, JM
Sippel, J
Nikolou, M
Kamaras, K
Reynolds, JR
Tanner, DB
Hebard, AF
Rinzler, AG [1 ]
机构
[1] Univ Florida, Dept Phys, Gainesville, FL 32611 USA
[2] Univ Florida, Dept Chem, Gainesville, FL 32611 USA
[3] MTA SzFKI, H-1525 Budapest, Hungary
关键词
D O I
10.1126/science.1101243
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
We describe a simple process for the fabrication of ultrathin, transparent, optically homogeneous, electrically conducting films of pure single-waited carbon nanotubes and the transfer of those films to various substrates. For equivalent sheet resistance, the films exhibit optical transmittance comparable to that of commercial indium tin oxide in the visible spectrum, but far superior transmittance in the technologically relevant 2- to 5-micrometer infrared spectral band. These characteristics indicate broad applicability of the films for electrical coupling in photonic devices. in an example application, the films are used to construct an electric field-activated optical modulator, which constitutes an optical analog to the nanotube-based field effect transistor.
引用
收藏
页码:1273 / 1276
页数:6
相关论文
共 17 条
[1]   Conducting Polymer (CP) infrared electrochromics in spacecraft thermal control and military applications [J].
Chandrasekhar, P ;
Zay, BJ ;
McQueeney, T ;
Scara, A ;
Ross, D ;
Birur, GC ;
Haapanen, S ;
Kauder, L ;
Swanson, T ;
Douglas, D .
SYNTHETIC METALS, 2003, 135 (1-3) :23-24
[2]  
Ginley D., 2001, MAT RES SOC S P, V668, pH2
[3]   Criteria for choosing transparent conductors [J].
Gordon, RG .
MRS BULLETIN, 2000, 25 (08) :52-57
[4]   Carbon nanotubes as Schottky barrier transistors [J].
Heinze, S ;
Tersoff, J ;
Martel, R ;
Derycke, V ;
Appenzeller, J ;
Avouris, P .
PHYSICAL REVIEW LETTERS, 2002, 89 (10)
[5]   Reversible modification of the absorption properties of single-walled carbon nanotube thin films via nitric acid exposure [J].
Hennrich, F ;
Wellmann, R ;
Malik, S ;
Lebedkin, S ;
Kappes, MM .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2003, 5 (01) :178-183
[6]   Preparation, characterization and applications of free-standing single walled carbon nanotube thin films [J].
Hennrich, F ;
Lebedkin, S ;
Malik, S ;
Tracy, J ;
Barczewski, M ;
Rösner, H ;
Kappes, M .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2002, 4 (11) :2273-2277
[7]   Spectroscopic study of the Fermi level electronic structure of single-walled carbon nanotubes [J].
Itkis, ME ;
Niyogi, S ;
Meng, ME ;
Hamon, MA ;
Hu, H ;
Haddon, RC .
NANO LETTERS, 2002, 2 (02) :155-159
[8]   Ballistic carbon nanotube field-effect transistors [J].
Javey, A ;
Guo, J ;
Wang, Q ;
Lundstrom, M ;
Dai, HJ .
NATURE, 2003, 424 (6949) :654-657
[9]   Electrochemical tuning of electronic structure of single-walled carbon nanotubes: In-situ Raman and vis-NIR study [J].
Kavan, L ;
Rapta, P ;
Dunsch, L ;
Bronikowski, MJ ;
Willis, P ;
Smalley, RE .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (44) :10764-10771
[10]   Amphoteric doping of single-wall carbon-nanotube thin films as probed by optical absorption spectroscopy [J].
Kazaoui, S ;
Minami, N ;
Jacquemin, R ;
Kataura, H ;
Achiba, Y .
PHYSICAL REVIEW B, 1999, 60 (19) :13339-13342