Surface-initiated polymerization on nanopatterns fabricated by electron-beam lithography

被引:117
作者
Ahn, SJ
Kaholek, M
Lee, WK
LaMattina, B
LaBean, TH
Zauscher, S [1 ]
机构
[1] Duke Univ, Dept Mech Engn & Mat Sci, Durham, NC 27708 USA
[2] Duke Univ, Ctr Biol Inspired Mat & Mat Syst, Durham, NC 27708 USA
[3] Duke Univ, Dept Comp Sci, Durham, NC 27708 USA
[4] Army Res Off, Res Triangle Pk, NC 27709 USA
关键词
D O I
10.1002/adma.200401055
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Micro- and nanopatterns of polymer brushes (see Figure) are fabricated using a "top-down/bottom-up" approach. A silicon surface is patterned with gold using lift-off electron-beam lithography ("top-down"), and the resulting pattern is then amplified by surf ace-initiated atom-transfer radical polymerization ("bottom-up") of N-isopropylacrylamide from an immobilized thiol initiator.
引用
收藏
页码:2141 / +
页数:6
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