Thermo labile Groups in Metal-Organic Frameworks: Suppression of Network Interpenetration, Post-Synthetic Cavity Expansion, and Protection of Reactive Functional Groups

被引：151

作者：

Deshpande, Rajesh K. ^{[1
]}

Minnaar, Jozeph L. ^{[1
]}

Telfer, Shane G. ^{[1
]}

机构：

[1] Massey Univ, Inst Fundamental Sci, MacDiarmid Inst Adv Mat & Nanotechnol, Palmerston North, New Zealand

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 27期

关键词：

interpenetration; metal-organic frameworks; porosity; protecting groups; zinc; POSTSYNTHETIC MODIFICATION; MOLECULES; TOPOLOGY; UNITS;

D O I：

10.1002/anie.200905960

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Creating nothing out of something: A bulky tert-butoxycarbonyl group on a biphenyl-4,4'-dicarboxylate ligand suppresses interpenetration to give an open, cubic metal-organic framework. Postsynthetic cleavage of this group by simple thermolysis (see picture) unmasks a potentially reactive amino functional group, increases the void space (yellow sphere), and widens the pore apertures. © 2010 Wiley-VCH Verlag GmbH S. Co. KGaA, Weinheim.

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收藏

页码：4598 / 4602

页数：5

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