Dye-sensitized solar tubes: A new solar cell design for efficient current collection and improved cell sealing

被引:56
作者
Tachan, Zion [1 ]
Ruhle, Sven [1 ]
Zaban, Arie [1 ]
机构
[1] Bar Ilan Univ, Dept Chem, Inst Nanotechnol & Adv Mat, IL-52900 Ramat Gan, Israel
关键词
Dye-sensitized solar cells; Dye-sensitized solar tubes; FTO synthesis; Spray pyrolysis; Current collector; Sealing; SNO2-F THIN-FILMS; ELECTROPHORETIC DEPOSITION; ELECTRICAL-PROPERTIES; TRANSPARENT; ELECTROLYTE;
D O I
10.1016/j.solmat.2009.10.006
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
A dye-sensitized solar cell (DSSC) fabricated inside a glass tube to form a dye-sensitized solar tube (DSST) is presented. We developed the synthesis of Fluorine-doped Tin oxide (FTO) with a high optical transmittance and low sheet resistance, which was deposited inside a glass tube by spray pyrolysis. The FTO was covered with a mesoporous TiO2 film using electrophoretic deposition (EPD). Subsequently the tube was sintered, sensitized with a Ru-dye (N3) and immersed into redox electrolyte while a Pt-coated rod closed the electrical circuit. Sealing of DSSCs is still a major problem. The new design reduces significantly the area that requires sealing compared to conventional flat cells, moreover sealing of a tube is significantly simpler than two flat plates. A huge advantage of the tube design is the possibility to incorporate a Current collector without blocking direct Sunlight front entering the cell. Panels consisting of DSSTs allow air flow in between the tubes, thus decreasing the wind resistivity while the cylindrical shape of the DSST can be used to collect diffuse light more effectively. Initial results on a prototype show a light to electric power conversion efficiency of 2.8%, demonstrating the feasibility of the new tube concept. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:317 / 322
页数:6
相关论文
共 26 条
[1]   Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies [J].
Bach, U ;
Lupo, D ;
Comte, P ;
Moser, JE ;
Weissörtel, F ;
Salbeck, J ;
Spreitzer, H ;
Grätzel, M .
NATURE, 1998, 395 (6702) :583-585
[2]   The influence of suspension composition and deposition mode on the electrophoretic deposition of TiO2 nanoparticle agglomerates [J].
Dor, S. ;
Ruhle, S. ;
Ofir, A. ;
Adler, M. ;
Grinis, L. ;
Zaban, A. .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2009, 342 (1-3) :70-75
[3]   Studies on structural and electrical properties of spray deposited SnO2:F thin films as a function of film thickness [J].
Elangovan, E ;
Singh, MP ;
Ramamurthi, K .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2004, 113 (02) :143-148
[4]  
FAN X, 2007, APPL PHYS LETT, V90
[5]   Wire-shaped flexible dye-sensitized solar cells [J].
Fan, Xing ;
Chu, Zengze ;
Wang, Fuzhi ;
Zhang, Chao ;
Chen, Lin ;
Tang, Yanwei ;
Zou, Dechun .
ADVANCED MATERIALS, 2008, 20 (03) :592-+
[6]   Solar Cell Efficiency Tables (Version 33) [J].
Green, Martin A. ;
Emery, Keith ;
Hishikawa, Yoshihiro ;
Warta, Wilhelm .
PROGRESS IN PHOTOVOLTAICS, 2009, 17 (01) :85-94
[7]   Electrophoretic deposition and compression of titania nanoparticle films for dye-sensitized solar cells [J].
Grinis, Larissa ;
Dor, Snir ;
Ofir, Ashi ;
Zaban, Arie .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2008, 198 (01) :52-59
[8]   Material development for dye solar modules:: Results from an integrated approach [J].
Hinsch, A. ;
Behrens, S. ;
Berginc, M. ;
Boennemann, H. ;
Brandt, H. ;
Drewitz, A. ;
Einsele, F. ;
Fassler, D. ;
Gerhard, D. ;
Gores, H. ;
Haag, R. ;
Herzig, T. ;
Himmler, S. ;
Khelashvili, G. ;
Koch, D. ;
Nazmutdinova, G. ;
Opara-Krasovec, U. ;
Putyra, P. ;
Rau, U. ;
Sastrawan, R. ;
Schauer, T. ;
Schreiner, C. ;
Sensfuss, S. ;
Siegers, C. ;
Skupien, K. ;
Wachter, P. ;
Walter, J. ;
Wasserscheid, P. ;
Wuerfel, U. ;
Zistler, M. .
PROGRESS IN PHOTOVOLTAICS, 2008, 16 (06) :489-501
[9]   High performance dye-sensitized solar cells using ionic liquids as their electrolytes [J].
Kawano, R ;
Matsui, H ;
Matsuyama, C ;
Sato, A ;
Susan, MABH ;
Tanabe, N ;
Watanabe, M .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2004, 164 (1-3) :87-92
[10]   New transparent conductive films: FTO coated ITO [J].
Kawashima, T ;
Matsui, H ;
Tanabe, N .
THIN SOLID FILMS, 2003, 445 (02) :241-244