Fluctuation theorem for currents and Schnakenberg network theory

被引：184

作者：

Andrieux, David ^{[1
]}

Gaspard, Pierre ^{[1
]}

机构：

[1] Univ Libre Bruxelles, Ctr Nonlinear Phenomena & Complex Syst, B-1050 Brussels, Belgium

来源：

JOURNAL OF STATISTICAL PHYSICS | 2007年 / 127卷 / 01期

关键词：

nonequilibrium steady state; entropy production; affinities; thermodynamic forces; fluctuation theorem;

D O I：

10.1007/s10955-006-9233-5

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

A fluctuation theorem is proved for the macroscopic currents of a system in a nonequilibrium steady state, by using Schnakenberg network theory. The theorem can be applied, in particular, in reaction systems where the affinities or thermodynamic forces are defined globally in terms of the cycles of the graph associated with the stochastic process describing the time evolution.

引用

页码：107 / 131

页数：25

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