A chloro-bridged (arene)Ru complex with a polymerizable side chain

被引：28

作者：

Wendicke, SB ^{[1
]}

Burri, E ^{[1
]}

Scopelliti, R ^{[1
]}

Severin, K ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Chim Mol & Biol, CH-1015 Lausanne, Switzerland

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 09期

关键词：

D O I：

10.1021/om020813r

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An [(arene)RuCl2](2) complex with a methacrylate side chain (2) has been prepared in two steps using commercially available starting materials. This complex reacts with PPh3, pyridine, or toluidine to give the corresponding mononuclear adducts (3-5). The structure of 4 was determined by single-crystal X-ray diffraction. Complex 2 and the PPh3 adduct 3 were immobilized by copolymerization with divinylbenzene (DVB) or ethyleneglycol dimethacrylate (EGDMA). The resulting EGDMA copolymer was tested as a catalyst in asymmetric transfer hydrogenations. Using (1R,2R)-(-)-N-p-tosyl-1,2-diphenylethylenediamine as the chiral ligand and azeotropic NEt3/HCO2H as the reducing agent, aromatic ketones were converted to the corresponding alcohols with selectivities between 87 and 97% ee.

引用

页码：1894 / 1897

页数：4

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