Efficient Synthesis of Aryl Fluorides

被引：82

作者：

Anbarasan, Pazhamalai ^{[1
]}

Neumann, Helfried ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 12期

关键词：

aryl fluorides; aryl halides; electrophilic fluorination; Grignard reagents; N-F reagents; CROSS-COUPLING REACTIONS; PALLADIUM-CATALYZED HYDROXYLATION; GRIGNARD-REAGENTS; FUNCTIONALIZED ARYLMAGNESIUM; MAGNESIUM-EXCHANGE; ALKYL-HALIDES; FLUORINATION; IRON; COMPLEXES; HALOGEN;

D O I：

10.1002/anie.200905855

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chemical Equation Presented" Creating C-F bonds: A novel electrophilic fluorination of aryl and heteroaryl Crignard reagents has been discovered and was used for the efficient synthesis of various aryl fluoride derivatives (see picture; THF = tetrahydrofuran). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA."

引用

页码：2219 / 2222

页数：4

共 68 条

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