Phosphorus-containing dendrimers and their transition metal complexes as efficient recoverable multicenter homogeneous catalysts in organic synthesis

被引:137
作者
Maraval, V [1 ]
Laurent, R [1 ]
Caminade, AM [1 ]
Majoral, JP [1 ]
机构
[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse 4, France
关键词
D O I
10.1021/om0005607
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Metalladendrimers of generation 3 with either 24 terminal palladium or ruthenium diphosphine complexes or one ruthenium diphosphine complex located at the core have been found to be efficient, recoverable catalysts in three general organic reactions: Stille couplings, Knoevenagel condensations, and Michael additions.
引用
收藏
页码:4025 / 4029
页数:5
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