Metal-Organic Framework Based on [Zn4O(COO)6] Clusters: Rare 3D Kagome Topology and Luminescence

被引：51

作者：

Yue, Qi ^{[1
]}

Sun, Qian ^{[1
]}

Cheng, Ai-Ling ^{[1
]}

Gao, En-Qing ^{[1
]}

机构：

[1] E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2010年 / 10卷 / 01期

关键词：

SECONDARY BUILDING UNITS; COORDINATION POLYMER; RETICULAR CHEMISTRY; DESIGN; MIL-68;

D O I：

10.1021/cg901312t

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A 2-fold interpenetrated metal-organic framework displaying intense yellow fluorescence is constructed from [Zn4O(COO)(6)] Clusters and it new dicarboxylate ligand hearing (lie fluorene chromophore flourene-2,7-dicarboxylic acid. The [Zn4O(COO)(6)] secondary building unit exhibits unusual coordination features and leads to the rare 3D pillared kagome net topology (3(2)4(8)6(5)).

引用

页码：44 / 47

页数：4

共 27 条

[1] VIII(OH){O2C-C6H4-CO2}•(HO2C-C6H4-CO2H)x(DMF)y(H2O)z (or MIL-68), a new vanadocarboxylate with a large pore hybrid topology:: reticular synthesis with infinite inorganic building blocks? [J].

Barthelet, K ;

Marrot, J ;

Férey, G ;

Riou, D .

CHEMICAL COMMUNICATIONS, 2004, (05) :520-521

[2] Synthesis of new two-photon absorbing fluorene derivatives via Cu-mediated Ullmann condensations [J].

Belfield, KD ;

Schafer, KJ ;

Mourad, W ;

Reinhardt, BA .

JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (15) :4475-4481

[3] Electronic and vibrational properties of a MOF-5 metal-organic framework: ZnO quantum dot behaviour [J].

Bordiga, S ;

Lamberti, C ;

Ricchiardi, G ;

Regli, L ;

Bonino, F ;

Damin, A ;

Lillerud, KP ;

Bjorgen, M ;

Zecchina, A .

CHEMICAL COMMUNICATIONS, 2004, (20) :2300-2301

[4] Design, chirality, and flexibility in nanoporous molecule-based materials [J].

Bradshaw, D ;

Claridge, JB ;

Cussen, EJ ;

Prior, TJ ;

Rosseinsky, MJ .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :273-282

[5] Unprecedented 3D entanglement of 1D zigzag coordination polymers leading to a robust microporous framework [J].

Cheng, Ai-Ling ;

Liu, Na ;

Yue, Yan-Feng ;

Jiang, Yong-Wen ;

Gao, En-Qing ;

Yan, Chun-Hua ;

He, Ming-Yuan .

CHEMICAL COMMUNICATIONS, 2007, (04) :407-409

[6] Discovery, synthesis, and characterization of an isomeric coordination polymer with pillared kagome net topology [J].

Chun, Hyungphil ;

Moon, Jumi .

INORGANIC CHEMISTRY, 2007, 46 (11) :4371-4373

[7] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].

Eddaoudi, M ;

Kim, J ;

Rosi, N ;

Vodak, D ;

Wachter, J ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2002, 295 (5554) :469-472

[8] Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks [J].

Eddaoudi, M ;

Moler, DB ;

Li, HL ;

Chen, BL ;

Reineke, TM ;

O'Keeffe, M ;

Yaghi, OM .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :319-330

[9] Magnetic ordering in diluted kagome antiferromagnets [J].

Frunzke, J ;

Hansen, T ;

Harrison, A ;

Lord, JS ;

Oakley, GS ;

Visser, D ;

Wills, AS .

JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (01) :179-185

[10] Geometrically frustrated magnetic materials [J].

Greedan, JE .

JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (01) :37-53

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