Synthesis and reactivity of sp2 geminated organobismetallic derivatives

被引：118

作者：

Marek, I ^{[1
]}

机构：

[1] Technion Israel Inst Technol, Dept Chem, IL-32000 Haifa, Israel

[2] Technion Israel Inst Technol, Inst Catalysis Sci & Technol, IL-32000 Haifa, Israel

来源：

CHEMICAL REVIEWS | 2000年 / 100卷 / 08期

关键词：

D O I：

10.1021/cr990288e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An overview is given on the synthesis and reactivity of sp2 geminal bis(metallic) systems =CMM′, M and M′ include various combinations of lithium, magnesium, aluminum, indium, gallium, zinc, zirconium, and titanium, with the ultimate achievement being a 1,1,2-trititanioalkene reagent generated from a 1-haloalkyne and a low-valent titanium intermediate.

引用

页码：2887 / 2900

页数：14

共 128 条

[1] UNUSUAL 1,2-MIGRATION IN ORGANOALUMINUM CHEMISTRY, PROMOTED BY BF3.0ET2 [J].

ALEXAKIS, A ;

HANAIZI, J ;

JACHIET, D ;

NORMANT, JF ;

TOUPET, L .

TETRAHEDRON LETTERS, 1990, 31 (09) :1271-1274

[2]

APELOIG Y, 1980, ISR J CHEM, V20, P43

[3] STABILIZATION OF PERPENDICULAR OLEFINS - STRUCTURES AND ROTATIONAL BARRIERS OF SINGLET AND TRIPLET 1,1-DILITHIOETHYLENES [J].

APELOIG, Y ;

SCHLEYER, PV ;

BINKLEY, JS ;

POPLE, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (14) :4332-4334

[4] ADDITION OF DI-T-BUTYLZINC TO SIMPLE AND FUNCTIONAL CONJUGATED ENYNE TRIPLE BONDS [J].

AUGER, J ;

COURTOIS, G ;

MIGINIAC, L .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 133 (03) :285-291

[5]

Averbuj C, 1999, SYNLETT, P1939

[6] THE COPPER(I)-CATALYZED COUPLING OF GRIGNARD-REAGENTS WITH 5-LITHIO-2,3-DIHYDROFURAN AND 6-LITHIO-3,4-DIHYDRO-2H-PYRAN [J].

BARBER, C ;

BURY, P ;

KOCIENSKI, P ;

OSHEA, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (22) :1595-1597

[7] STANNYL-CUPRATION OF ACETYLENES AND THE REACTION OF THE INTERMEDIATE CUPRATES WITH ELECTROPHILES AS A SYNTHESIS OF SUBSTITUTED VINYLSTANNANES [J].

BARBERO, A ;

CUADRADO, P ;

FLEMING, I ;

GONZALEZ, AM ;

PULIDO, FJ ;

RUBIO, R .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1993, (14) :1657-1662

[8] THE STANNYL CUPRATION OF ACETYLENES AND THE REACTION OF THE INTERMEDIATE CUPRATES WITH ELECTROPHILES AS A SYNTHESIS OF SUBSTITUTED VINYLSTANNANES [J].

BARBERO, A ;

CUADRADO, P ;

FLEMING, I ;

GONZALEZ, AM ;

PULIDO, FJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (04) :351-353

[9] SYNTHESIS OF 2-FUNCTIONALIZED 1,1-DIIODO-1-ALKENES - GENERATION AND REACTIONS OF 1-IODO-1-LITHIO-1-ALKENES AND 1,1-DILITHIO-1-ALKENES [J].

BARLUENGA, J ;

RODRIGUEZ, MA ;

CAMPOS, PJ ;

ASENSIO, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (16) :5567-5568

[10] Zirconium-mediated intramolecular coupling of terminal alkynes and their subsequent carbonylation: Novel synthesis of seven- and eight-membered heterocycles [J].

Barluenga, J ;

Sanz, R ;

Fananas, FJ .

CHEMISTRY-A EUROPEAN JOURNAL, 1997, 3 (08) :1324-1336

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