Synthesis and reactivity of sp2 geminated organobismetallic derivatives

被引：118

作者：

Marek, I ^{[1
]}

机构：

[1] Technion Israel Inst Technol, Dept Chem, IL-32000 Haifa, Israel

[2] Technion Israel Inst Technol, Inst Catalysis Sci & Technol, IL-32000 Haifa, Israel

来源：

CHEMICAL REVIEWS | 2000年 / 100卷 / 08期

关键词：

D O I：

10.1021/cr990288e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An overview is given on the synthesis and reactivity of sp2 geminal bis(metallic) systems =CMM′, M and M′ include various combinations of lithium, magnesium, aluminum, indium, gallium, zinc, zirconium, and titanium, with the ultimate achievement being a 1,1,2-trititanioalkene reagent generated from a 1-haloalkyne and a low-valent titanium intermediate.

引用

页码：2887 / 2900

页数：14

共 128 条

[71] On the regiochemistry of cyclialkylation of regiodefined 4-halo-1-alkenylmetals producing cyclobutenes [J].

Liu, F ;

Negishi, E .

TETRAHEDRON LETTERS, 1997, 38 (07) :1149-1152

[72] Formation and rearrangement of gem-dilithiodiphenylethene [J].

Maercker, A ;

Bos, B ;

Hajgholipour, MT .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 566 (1-2) :143-149

[73] POLYLITHIUM ORGANIC-COMPOUNDS .2. DILITHIOMETHYLENECYCLOHEXANE - A STABLE 1,1-DILITHIOALKENE [J].

MAERCKER, A ;

DUJARDIN, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1984, 23 (03) :224-224

[74] SUCCESSFUL X-RAY STRUCTURE-ANALYSIS OF AN ALKYLIDENE CARBENOID - A MILESTONE IN CARBENOID RESEARCH [J].

MAERCKER, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (07) :1023-1025

[75] POLYLITHIUM ORGANIC-COMPOUNDS .4. 2,3-DILITHIO-1,3-BUTADIENES VIA ADDITION OF LITHIUM TO BUTATRIENES [J].

MAERCKER, A ;

DUJARDIN, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1985, 24 (07) :571-572

[76]

Maercker A., 1987, TOP CURR CHEM, V138, P1

[77]

Maercker A., 1995, LITHIUM CHEM, P490

[78]

Maercker A., 1991, MAIN GROUP MET CHEM, V14, P67

[79] DIASTEREOSELECTIVE CARBOMETALATION OF VINYLMETALS [J].

MAREK, I ;

LEFRANCOIS, JM ;

NORMANT, JF .

JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (15) :4154-4161

[80]

MAREK I, 1994, B SOC CHIM FR, V131, P910

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