Synthesis and reactivity of sp2 geminated organobismetallic derivatives

被引：118

作者：

Marek, I ^{[1
]}

机构：

[1] Technion Israel Inst Technol, Dept Chem, IL-32000 Haifa, Israel

[2] Technion Israel Inst Technol, Inst Catalysis Sci & Technol, IL-32000 Haifa, Israel

来源：

CHEMICAL REVIEWS | 2000年 / 100卷 / 08期

关键词：

D O I：

10.1021/cr990288e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An overview is given on the synthesis and reactivity of sp2 geminal bis(metallic) systems =CMM′, M and M′ include various combinations of lithium, magnesium, aluminum, indium, gallium, zinc, zirconium, and titanium, with the ultimate achievement being a 1,1,2-trititanioalkene reagent generated from a 1-haloalkyne and a low-valent titanium intermediate.

引用

页码：2887 / 2900

页数：14

共 128 条

[61] A STRUCTURALLY DISTORTED LIGAND IN AN ELECTRON-DEFICIENT DIZIRCONOCENE CATION - UNUSUAL 1,2-DIMETALLIOALKENES AND 1,1-DIMETALLIOALKENES [J].

HORTON, AD ;

ORPEN, AG .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (07) :876-878

[62] Monomeric bis(eta(2)-alkyne) complexes of copper(I) and silver(I) with eta(1)-bonded alkyl, vinyl, and aryl ligands [J].

Janssen, MD ;

Kohler, K ;

Herres, M ;

Dedieu, A ;

Smeets, WJJ ;

Spek, AL ;

Grove, DM ;

Lang, H ;

vanKoten, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (20) :4817-4829

[63] PREPARATION OF POLYFUNCTIONAL NITRILES BY THE CYANATION OF FUNCTIONALIZED ORGANOZINC HALIDES WITH P-TOLUENESULFONYL CYANIDE [J].

KLEMENT, I ;

LENNICK, K ;

TUCKER, CE ;

KNOCHEL, P .

TETRAHEDRON LETTERS, 1993, 34 (29) :4623-4626

[64] ELIMINATIONS FROM OLEFINS [J].

KOBRICH, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1965, 4 (01) :49-&

[65]

Kocienski P., 1993, -Heteroalkenyl Metallate Rearrangements in Organic Synthesis, P203

[66]

Kulinkovich O. G., 1989, J ORG CHEM USSR, V25, P2027

[67]

KULINKOVICH OG, 1989, ZH ORG KHIM+, V25, P2244

[68] TITANIUM(IV) ISOPROPOXIDE-CATALYZED FORMATION OF 1-SUBSTITUTED CYCLOPROPANOLS IN THE REACTION OF ETHYLMAGNESIUM BROMIDE WITH METHYL ALKANECARBOXYLATES [J].

KULINKOVICH, OG ;

SVIRIDOV, SV ;

VASILEVSKI, DA .

SYNTHESIS-STUTTGART, 1991, (03) :234-234

[69] GENERATION OF ALKYLIDENECARBENES FROM 1,1-DIBROMOALK-1-ENES BY THE REACTION WITH SAMARIUM DIIODIDE IN HEXAMETHYLPHOSPHORIC TRIAMIDE BENZENE [J].

KUNISHIMA, M ;

HIOKI, K ;

OHARA, T ;

TANI, S .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (03) :219-220

[70] 1,1-DILITHIOETHYLENE - GROUND-STATE TRIPLET OLEFIN WITH NEARLY FREE ROTATION ABOUT THE DOUBLE-BOND [J].

LAIDIG, WD ;

SCHAEFER, HF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (24) :7184-7188

← 2 3 4 5 6 7 8 9 10 11 →