Self-assembly of one-dimensional coordination polymer from nickel(II) macrocyclic complex and 2,6-pyridinedicarboxylate ligand

被引：43

作者：

Choi, KY ^{[1
]}

Ryu, H

Lim, YM

Sung, ND

Shin, US

Suh, M

机构：

[1] Kongju Natl Univ, Dept Chem Educ, Kong Ju 314701, South Korea

[2] Chungnam Natl Univ, Res Ctr Transgen Cloned Pigs, Div Appl Biol & Chem, Taejon 305764, South Korea

[3] Rhein Westfal TH Aachen, Inst Inorgan Chem, D-52056 Aachen, Germany

[4] Kongju Natl Univ, Dept Geoenvironm Sci, Kong Ju 314701, South Korea

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 04期

基金：

欧洲研究理事会;

关键词：

crystal structure; nickel(II) complex; antiferromagnetic interaction; one-dimensional polymer; 2,6-pyridinedicarboxylate;

D O I：

10.1016/S1387-7003(02)00802-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Ni(L)(H2O)(2)]Cl-2 (L = 2,5,9,12-tetramethyl-1,4,8,1 1-tetraazacyclotetradecane) with 2,6-pyridinedicarboxylate (pdc) generates one-dimensional coordination polymer [Ni(L) (pdc)] . H2O (1). In the polymeric framework, the nickel(II) ion has an octahedral geometry and is bridged by two pdc ligands. The magnetic susceptibility measurement for 1 exhibits a weak antifer-romagnetic interaction (J = -1.04(3) cm(-1); H = -JSigmaS(i) . Si+1) between the S = I nickel(II) paramagnetic centers. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：412 / 415

页数：4

共 25 条

[11] Chemistry and physics of supramolecular magnetic materials [J].