Quasi-thermoneutral P → B interactions within Di- and tri-phosphine boranes

被引：79

作者：

Bontemps, Sebastien

Bouhadir, Ghenwa

Dyer, Philip W.

Miqueu, Karinne

Bourissou, Didier

机构：

[1] Univ Toulouse 3, CNRS, UMR 5069, Lab Heterochim Fondamentale & Appl, F-31062 Toulouse 09, France

[2] Univ Durham, Dept Chem, Durham DH1 3LE, England

[3] Univ Pau & Pays Adour, F-64013 Pau, France

[4] IPREM, UMR 5254, Equipe Chim Phys, F-64013 Pau, France

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 13期

关键词：

D O I：

10.1021/ic7006556

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Spectroscopic, structural, and theoretical evidence is provided for both open (no intramolecular P -> B interaction) and closed (with intramolecular P -> B interaction) forms of the di- and tri-phosphine boranes [o-(iPr(2)P)C6H4](2)BPh (2) and [o-(iPr(2)P)C6H4](3)B (3).

引用

页码：5149 / 5151

页数：3

共 36 条

[11] ANIONIC AND STERIC FACTORS GOVERNING COORDINATIVE UNSATURATION AT CARBENIC PHOSPHENIUM CENTERS [J].