First hypervalent iodine(III)-catalyzed C-N bond forming reaction:: catalytic spirocyclization of amides to N-fused spirolactams

被引：193

作者：

Dohi, Toshifumi ^{[1
]}

Maruyama, Akinobu ^{[1
]}

Minamitsuji, Yutaka ^{[1
]}

Takenaga, Naoko ^{[1
]}

Kita, Yasuyuki ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Pharmaceut Sci, Suita, Osaka 5650871, Japan

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 12期

关键词：

D O I：

10.1039/b616510a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A protic solvent, 2,2,2-trifluoroethanol (CF3CH2OH), was successfully introduced into hypervalent iodine(III)-involved catalytic cycles as an effective solvent, and the first iodoarene-catalyzed intramolecular carbon-nitrogen bond forming reaction was achieved under strong acid-free and mild conditions.

引用

页码：1224 / 1226

页数：3

共 35 条

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