The first stable scandocene:: synthesis and characterisation of bis(η-2,4,5-tri-tert-butyl-1,3-diphosphacyclopentadienyl)scandium(II)

被引：60

作者：

Arnold, PL ^{[1
]}

Cloke, FGN ^{[1
]}

Nixon, JF ^{[1
]}

机构：

[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 07期

关键词：

D O I：

10.1039/a800089a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first isolable example of a molecular scandium(II) complex, the dark purple scandocene [Sc(eta(5)-P2C3Bu3t)] 1, has been isolated from the cocondensation of scandium vapour with tert-butylphosphaalkyne, (BuCP)-C-t at 77 K.

引用

页码：797 / 798

页数：2

共 22 条

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