A recyclable nanosize aminoarenethiolato copper(I) catalyst for C-C coupling reactions

被引：10

作者：

Arink, AM ^{[1
]}

van de Coevering, R ^{[1
]}

Wieczorek, B ^{[1
]}

Firet, J ^{[1
]}

Jastrzebski, JTBH ^{[1
]}

Gebbink, RJMK ^{[1
]}

van Koten, G ^{[1
]}

机构：

[1] Univ Utrecht, Debye Res Inst, Dept Met Mediated Synth, NL-3584 CH Utrecht, Netherlands

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2004年 / 689卷 / 23期

关键词：

aminoarenethiolate; copper catalyst; carbosilane dendrimer; catalysis; nanofiltration; recycling;

D O I：

10.1016/j.jorganchem.2004.07.023

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An aminoarenethiolato copper(I) catalyst was attached to a carbosilane dendritic wedge, which had been prepared via a novel convergent synthetic method. Compared with the unsupported complex, this novel dendritic copper(I) catalyst is more robust towards hydrolysis and oxidation and has increased solubility in common organic solvents. The catalytic activity of the dendritic, copper catalyst was tested in the 1,4-addition of Et2Zn to 2-cyclohexenone. In both polar (Et2O) and apolar (hexane) solvents excellent activity was observed. The fact that the catalytic copper site remains attached to the nanosize dendritic aminoarenethiolate ligand allows separation of this catalyst by means of nanofiltration. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：3813 / 3819

页数：7

共 27 条

[21] ENANTIOSELECTIVE COPPER-CATALYZED 1,4-ADDITION OF GRIGNARD-REAGENTS TO ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS [J].

SPESCHA, M ;

RIHS, G .

HELVETICA CHIMICA ACTA, 1993, 76 (03) :1219-1230

[22] Dendrimers as support for recoverable catalysts and reagents [J].

van Heerbeek, R ;

Kamer, PCJ ;

van Leeuwen, PWNM ;

Reek, JNH .

CHEMICAL REVIEWS, 2002, 102 (10) :3717-3756

[23] Polymeric membranes in catalytic reactors [J].

Vankelecom, IFJ .

CHEMICAL REVIEWS, 2002, 102 (10) :3779-3810

[24] ARENETHIOLATOCOPPER(I) COMPLEXES AS HOMOGENEOUS CATALYSTS FOR MICHAEL ADDITION-REACTIONS [J].

VANKLAVEREN, M ;

LAMBERT, F ;

EIJKELKAMP, DJFM ;

GROVE, DM ;

VANKOTEN, G .

TETRAHEDRON LETTERS, 1994, 35 (33) :6135-6138

[25] CHIRAL ARENETHIOLATOCOPPER(I) CATALYZED SUBSTITUTION-REACTIONS OF ACYCLIC ALLYLIC SUBSTRATES WITH GRIGNARD-REAGENTS [J].

VANKLAVEREN, M ;

PERSSON, ESM ;

DELVILLAR, A ;

GROVE, DM ;

BACKVALL, JE ;

VANKOTEN, G .

TETRAHEDRON LETTERS, 1995, 36 (17) :3059-3062

[26] Dendrimers supported by the [Re6Se8]2+ metal cluster core [J].

Wang, RY ;

Zheng, ZP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (14) :3549-3550

[27]

ZHOU QL, 1994, TETRAHEDRON, V50, P4467

← 1 2 3 →