Construction of spiro-oxaquinolizidinone framework of Upenamide via organoiron complexes

被引：11

作者：

Han, Jeng Liang ^{[1
]}

Ong, Chi Wi ^{[1
]}

机构：

[1] Natl Sun Yat Sen Univ, Dept Chem, Kaohsiung 804, Taiwan

来源：

TETRAHEDRON | 2007年 / 63卷 / 03期

关键词：

D O I：

10.1016/j.tet.2006.11.018

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An organoiron approach toward the synthesis of an elaborated tricyclic spiro-oxaquinolizidinone ring has been accomplished. The key intermediate was efficiently prepared through a nitrile addition to the appropriately functionalized cyclohexadienylium-Fe(CO)(3) perchlorate salt to install the requisite quaternary center in the spiro-oxaquinolizidinone ring. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：609 / 614

页数：6

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