Helix induction in an optically inactive poly[(4-carboxyphenyl)acetylene] film with chiral amines

被引：10

作者：

Maeda, K ^{[1
]}

Hatanaka, K ^{[1
]}

Yashima, E ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Engn, Dept Mol Design & Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan

来源：

MENDELEEV COMMUNICATIONS | 2004年 / 14卷 / 06期

关键词：

D O I：

10.1070/MC2004v014n06ABEH002074

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An optically inactive cis-transoidal poly [(4-carboxyphenyl)acetylene] was found to form a predominantly one-handed helical conformation upon complexation with optically active amines and amino alcohols in the solid state, resulting in a characteristic induced circular dichroism in the polymer backbone region.

引用

页码：231 / 233

页数：3

共 25 条

[11] A helical polyelectrolyte induced by specific interactions with biomolecules in water [J].

Onouchi, H ;

Maeda, K ;

Yashima, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (30) :7441-7442

[12] Controlled incorporation of water molecules into carboxy hydrogen-bond networks:: A designed approach [J].

Pérez, C ;

Rodríguez, ML ;

Foces-Foces, C ;

Pérez-Hernández, N ;

Pérez, R ;

Martín, JD .

ORGANIC LETTERS, 2003, 5 (05) :641-644

[13] Understanding solid/solid organic reactions [J].

Rothenberg, G ;

Downie, AP ;

Raston, CL ;

Scott, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (36) :8701-8708

[14] Synthesis and macromolecular helicity induction of a stereoregular polyacetylene bearing a carboxy group with natural amino acids in water [J].

Saito, MA ;

Maeda, K ;

Onouchi, H ;

Yashima, E .

MACROMOLECULES, 2000, 33 (13) :4616-4618

[15] PRESSURE-INDUCED CIS TO TRANS ISOMERIZATION OF POLY(O-METHOXYPHENYLACETYLENE) POLYMERIZED BY RH COMPLEX CATALYST - A RAMAN, X-RAY, AND ESR STUDY [J].

TABATA, M ;

TAKAMURA, H ;

YOKOTA, K ;

NOZAKI, Y ;

HOSHINA, T ;

MINAKAWA, H ;

KODAIRA, K .

MACROMOLECULES, 1994, 27 (21) :6234-6236

[16] Solvent-free organic synthesis [J].

Tanaka, K ;

Toda, F .

CHEMICAL REVIEWS, 2000, 100 (03) :1025-1074

[17] Chiral information transfer by solid-solid interaction: application for absolute configuration assignment [J].

Tanaka, Y ;

Murakami, Y ;

Kiko, R .

CHEMICAL COMMUNICATIONS, 2003, (01) :160-161

[18] Chiral inclusion crystals constructed with achiral host and achiral guest molecules [J].

Toda, F .

ENANTIOMER, 2002, 7 (2-3) :59-65

[19] Solid state organic chemistry: Efficient reactions, remarkable yields, and stereoselectivity [J].

Toda, F .

ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (12) :480-486

[20] POLY((4-CARBOXYPHENYL)ACETYLENE) AS A PROBE FOR CHIRALITY ASSIGNMENT OF AMINES BY CIRCULAR-DICHROISM [J].

YASHIMA, E ;

MATSUSHIMA, T ;

OKAMOTO, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (46) :11596-11597

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