Ionic interaction as a powerful driving force for the formation of heterobidentate assembly ligands

被引：53

作者：

Gulyas, Henrik ^{[1
]}

Benet-Buchholz, Jordi ^{[1
]}

Escudero-Adan, Eduardo C. ^{[1
]}

Freixa, Zoraida ^{[1
]}

van Leeuwen, Piet W. N. M. ^{[1
]}

机构：

[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2007年 / 13卷 / 12期

关键词：

chelating ligands; combinatorial chemistry; ion pairs; phosphanes; self-assembly;

D O I：

10.1002/chem.200601640

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An ionic interaction has been used for the first time to assemble mono phosphane ligands. NMR spectroscopy and X-ray studies show that cationic and anionic triphenylphosphane derivatives form ion pairs and subsequently act. as a ligand in various transition-metal complexes. The position of the ionic functional groups allows both cis and trans coordination of the novel assembly ligand in square-planar transition-metal complexes

引用

页码：3424 / 3430

页数：7

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