A Metal-Organic Framework with Covalently Bound Organometallic Complexes

被引：198

作者：

Oisaki, Kounosuke ^{[1
]}

Li, Qiaowei ^{[1
]}

Furukawa, Hiroyasu ^{[1
]}

Czaja, Alexander U. ^{[2
]}

Yaghi, Omar M. ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Dept Chem & Biochem, Ctr Reticular Chem, Los Angeles, CA 90095 USA

[2] Calif NanoSyst Inst, BASF SE, GCC PZ, Los Angeles, CA 90095 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 27期

关键词：

N-HETEROCYCLIC CARBENE; IMIDAZOLIUM DICARBOXYLATE; COPPER COMPLEXES; DESIGN; CHEMISTRY; CATALYST; BASE;

D O I：

10.1021/ja103016y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A procedure for making covalently linked organometallic complexes within the pores of metal organic frameworks (MOFs) has been described. An N-heterocyclic carbene precursor containing link L0 was prepared and then constructed into a MOF-5-type structure (IRMOF-76). Attempts to produce covalently bound organometallic complexes in IRMOF-76 were unsuccessful. An alternative way of linking the first metalated link, L1, into the desired metalated MOF structure, IRMOF-77, was successful. IRMOF-76 and -77 were characterized by single-crystal X-ray studies. Demonstration of permanent porosity and successful substitution of the pyridine coligand in IRMOF-77 are also described.

引用

页码：9262 / 9264

页数：3

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