Design principles of fluorescent molecular sensors for cation recognition

被引:2300
作者
Valeur, B
Leray, I
机构
[1] ENS Cachan, Dept Chim, CNRS, UMR 8531,Lab PPSM, F-94235 Cachan, France
[2] Conservatoire Natl Arts & Metiers, Lab Chim Gen, F-75141 Paris 03, France
关键词
fluorescent molecular sensors; cation recognition; photoinduced electron transfer; photoinduced charge transfer; excimers;
D O I
10.1016/S0010-8545(00)00246-0
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The main classes of fluorescent molecular sensors for cation recognition are presented: they differ by the nature of the cation-controlled photoinduced processes: photoinduced electron transfer, photoinduced charge transfer, excimer formation or disappearance. In each class, distinction is made according to the structure of the complexing moiety: chelators, podands, coronands (crown ethers), cryptands, calixarenes. The most representative examples are presented in each subclass with special attention given to selectivity. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:3 / 40
页数:38
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