Lamellar assembly of conical molecules possessing a fullerene apex in crystals and liquid crystals

被引：84

作者：

Zhong, Yu-Wu ^{[1
]}

Matsuo, Yutaka ^{[1
]}

Nakamura, Eiichi ^{[1
]}

机构：

[1] Univ Tokyo, JST, ERATO, Nakamura Funct Carbon Cluster Project,Bunkyo Ku, Tokyo 1130033, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 11期

关键词：

D O I：

10.1021/ja068780k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Shuttlecock molecules made of fullerene and five side chains that have previously been shown to self-assemble into a polar columnar structure are now made into a lamellar structure in crystals and liquid crystals. The molecular design is such that the conical molecules C-60((C6H4CCSiMe2CnH2n+1)-C-n)(5)Me form crystals when the silicon substituent is a methyl group and that they form smectic liquid crystals when one of them is a long hydrocarbon chain. The fullerene groups in each layer interact with each other very strongly, suggesting that such lamellar structures may be useful for organic electronics applications.

引用

页码：3052 / +

页数：3

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