Research Development on Sodium-Ion Batteries

被引:5459
作者
Yabuuchi, Naoaki [1 ,2 ]
Kubota, Kei [1 ,2 ]
Dahbi, Mouad [1 ,2 ]
Komaba, Shinichi [1 ,2 ]
机构
[1] Tokyo Univ Sci, Dept Appl Chem, Shinjuku Ku, Tokyo 1628061, Japan
[2] Kyoto Univ, ESICB, Kyoto 6158520, Japan
关键词
SOLID-ELECTROLYTE INTERPHASE; GRAPHITE NEGATIVE ELECTRODES; PERFORMANCE ANODE MATERIAL; ELECTRICAL ENERGY-STORAGE; HIGH-CAPACITY CATHODE; LIQUID NAFSA-KFSA; X-RAY-DIFFRACTION; LONG CYCLE LIFE; LITHIUM-ION; POSITIVE-ELECTRODE;
D O I
10.1021/cr500192f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The material's abundance is a simple and clear reason as to why sodium ions are attractive as charge carriers for rechargeable batteries. It is also expected that potassium ions have a further smaller desolvation energy compared with the Li and Na systems in aprotic solvents. However, further energy sacrifice is also unavoidable for the potassium system due to heavy atomic weight. In addition to the oxides, a wide variety of crystal structures is known for polyanionic compounds and the structural chemistry of the Na system is much more complicated in comparison to the Li system. Na ions are apparently coordinated by four fluoride ions at bottleneck sites when the Na ions migrate across the perovskite-type framework structure.
引用
收藏
页码:11636 / 11682
页数:47
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