Enhancement of peroxygenase activity of horse heart myoglobin by modification of heme-propionate side chains

被引：15

作者：

Hayashi, T ^{[1
]}

Matsuda, T ^{[1
]}

Hisaeda, Y ^{[1
]}

机构：

[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Fukuoka 8128581, Japan

来源：

CHEMISTRY LETTERS | 2003年 / 32卷 / 06期

关键词：

D O I：

10.1246/cl.2003.496

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A myoglobin reconstituted with an artificially created heme having two benzene moieties bound at the terminal of two heme-propionates shows a clear enhancement in peroxygenase activity toward thioether and styrene oxidations due to the expanding hydrophobic heme pocket.

引用

页码：496 / 497

页数：2

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