Effect of Al2O3 capping layer on suppression of interfacial SiO2 growth in HfO2/ultrathin SiO2/Si(001) structure

被引:21
作者
Kundu, M [1 ]
Miyata, N
Nabatame, T
Horikawa, T
Ichikawa, M
Toriumi, A
机构
[1] AIST, MIRAI Project, ASRC, Tsukuba, Ibaraki 3058562, Japan
[2] Assoc Super Adv Elect Technol, MIRAI Project, Tsukuba, Ibaraki 3058569, Japan
[3] Univ Tokyo, Bunkyo Ku, Tokyo 1138656, Japan
关键词
D O I
10.1063/1.1576293
中图分类号
O59 [应用物理学];
学科分类号
摘要
We investigated the effect a 1.2-nm-thick Al2O3 capping layer had on suppressing interfacial Si oxidation in a 2.6-nm-HfO2/0.35-nm-SiO2/Si(001) structure during postdeposition annealing in an oxygen ambient. An incubation period (IP) was initially observed during which the HfO2/Si interface exhibited remarkable stability without any interfacial SiO2 growth. This was then followed by very slow interface oxidation. Our detailed study suggested that low oxidant diffusion through the capping layer determined the effective IP. Furthermore, HfO2/Si interface oxidation, which proceeded through a two-step process that was similar to an uncapped structure, was severely constrained by the limited availability of oxygen at the Al2O3/HfO2 interface. (C) 2003 American Institute of Physics.
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页码:3442 / 3444
页数:3
相关论文
共 14 条
[1]   Interface reactions of high-κ Y2O3 gate oxides with Si [J].
Busch, BW ;
Kwo, J ;
Hong, M ;
Mannaerts, JP ;
Sapjeta, BJ ;
Schulte, WH ;
Garfunkel, E ;
Gustafsson, T .
APPLIED PHYSICS LETTERS, 2001, 79 (15) :2447-2449
[2]   Thermal stability and structural characteristics of HfO2 films on Si (100) grown by atomic-layer deposition [J].
Cho, MH ;
Roh, YS ;
Whang, CN ;
Jeong, K ;
Nahm, SW ;
Ko, DH ;
Lee, JH ;
Lee, NI ;
Fujihara, K .
APPLIED PHYSICS LETTERS, 2002, 81 (03) :472-474
[3]   Mechanism of interstitial oxygen diffusion in hafnia [J].
Foster, AS ;
Shluger, AL ;
Nieminen, RM .
PHYSICAL REVIEW LETTERS, 2002, 89 (22) :225901-225901
[4]   Compatibility of polycrystalline silicon gate deposition with HfO2 and Al2O3/HfO2 gate dielectrics [J].
Gilmer, DC ;
Hegde, R ;
Cotton, R ;
Garcia, R ;
Dhandapani, V ;
Triyoso, D ;
Roan, D ;
Franke, A ;
Rai, R ;
Prabhu, L ;
Hobbs, C ;
Grant, JM ;
La, L ;
Samavedam, S ;
Taylor, B ;
Tseng, H ;
Tobin, P .
APPLIED PHYSICS LETTERS, 2002, 81 (07) :1288-1290
[5]   Interface reactions in ZrO2 based gate dielectric stacks [J].
Gribelyuk, MA ;
Callegari, A ;
Gusev, EP ;
Copel, M ;
Buchanan, DA .
JOURNAL OF APPLIED PHYSICS, 2002, 92 (03) :1232-1237
[6]   Effect of oxygen pressure on the structure and thermal stability of ultrathin Al2O3 films on Si(001) [J].
Kundu, M ;
Ichikawa, M ;
Miyata, N .
JOURNAL OF APPLIED PHYSICS, 2002, 91 (01) :492-500
[7]   THERMAL-OXIDATION OF SILICON IN DRY OXYGEN GROWTH-RATE ENHANCEMENT IN THE THIN REGIME .1. EXPERIMENTAL RESULTS [J].
MASSOUD, HZ ;
PLUMMER, JD ;
IRENE, EA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1985, 132 (11) :2685-2693
[8]   Thermal stability of a thin HfO2/ultrathin SiO2/Si structure:: Interfacial Si oxidation and silicidation [J].
Miyata, N ;
Ichikawa, M ;
Nabatame, T ;
Horikawa, T ;
Toriumi, A .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 2003, 42 (2B) :L138-L140
[9]   THERMAL-DECOMPOSITION OF NATIVE-OXIDE ON SI(100) [J].
MIYATA, N ;
SHIGENO, M ;
ARIMOTO, Y ;
ITO, T .
JOURNAL OF APPLIED PHYSICS, 1993, 74 (08) :5275-5276
[10]  
Nabatame T., 2002, 2002 INT C SOL STAT, P64