Spectroscopic ellipsometry of graphene and an exciton-shifted van Hove peak in absorption

被引:492
作者
Kravets, V. G. [1 ]
Grigorenko, A. N. [1 ]
Nair, R. R. [1 ]
Blake, P. [1 ]
Anissimova, S. [1 ]
Novoselov, K. S. [1 ]
Geim, A. K. [1 ]
机构
[1] Univ Manchester, Sch Phys & Astron, Manchester M13 9PL, Lancs, England
关键词
D O I
10.1103/PhysRevB.81.155413
中图分类号
T [工业技术];
学科分类号
120111 [工业工程];
摘要
We demonstrate that optical transparency of any two-dimensional system with a symmetric electronic spectrum is governed by the fine structure constant and suggest a simple formula that relates a quasiparticle spectrum to an optical absorption of such a system. These results are applied to graphene deposited on a surface of oxidized silicon for which we measure ellipsometric spectra, extract optical constants of a graphene layer and reconstruct the electronic dispersion relation near the K point using optical transmission spectra. We also present spectroscopic ellipsometry analysis of graphene placed on amorphous quartz substrates and report a pronounced peak in ultraviolet absorption at 4.6 eV because of a van Hove singularity in graphene's density of states. The peak is asymmetric and downshifted by 0.5 eV probably due to excitonic effects.
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页数:6
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