Cost efficient synthesis of amides from oximes with indium or zinc catalysts

被引：88

作者：

Allen, C. Liana ^{[1
]}

Burel, Celine ^{[1
]}

Williams, Jonathan M. J. ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

TETRAHEDRON LETTERS | 2010年 / 51卷 / 20期

基金：

英国工程与自然科学研究理事会;

关键词：

ONE-POT SYNTHESIS; BECKMANN REARRANGEMENT; HIGHLY EFFICIENT; MICROWAVE IRRADIATION; BOND FORMATION; SOLVENT-FREE; ALDEHYDES; NITRILES; CONVERSION; ALDOXIMES;

D O I：

10.1016/j.tetlet.2010.03.048

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Simple indium and zinc salts have been successfully used as catalysts for the rearrangement of oximes into primary amides. The direct synthesis of nitriles or primary amides from aldehydes has also been demonstrated using these inexpensive catalysts. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：2724 / 2726

页数：3

共 36 条

[31] Amide bond formation: beyond the myth of coupling reagents [J].